Journal
ORGANIC LETTERS
Volume 8, Issue 12, Pages 2651-2652Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol061002c
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The first total synthesis of pterocellin A (1) was achieved in 10 linear steps from commercially available kojic acid (6) and 2-bromo-3-pyridinol (11) in a convergent sequence. The key constructive steps are a directed lithiation to couple two pyridines and an intramolecular nucleophilic aromatic substitution to form 1.
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