Mapping electrochemiluminescence as generated at double-band microelectrodes by confocal microscopy under steady state

A confocal microspectrometer was used to collect spatially resolved electrochemiluminescence (ECL) spectra from the annihilation reaction between Ru(bpy)(3)(+) and Ru(bpy)(3)(3+), each species being generated at a platinum band microelectrode and separated by a micrometric insulating gap. The use of a confocal microspectrometer allows in situ photon detection of the ECL reaction with micrometric spatial resolution and observes the concentration distribution of the photon source in the vicinity of the interelectrode gap.