Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 12, Issue 18, Pages 4893-4899Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200501635
Keywords
discorhabdin A; hypervalent iodine reagents; N,O-acetal; natural products; synthetic methods
Categories
Ask authors/readers for more resources
Hypervalent iodine(m) reagents are readily available, easy to handle, and have a low toxicity and similar reactivities to those of heavy metal reagents, and hence they are used for various oxidative reactions. The oxidative cleavage of alkynes or carbonyl compounds by using bis(trifluoroacetoxy)iodo(III) pentafluoro-benzene (C6F5I(OCOCF3)(2)) has been reported.([1]) Herein, the efficient direct synthesis of NO-acetal compounds as key intermediates of discorhabdin A, by the oxidative fragmentation reaction of alpha-amino acids or beta-amino alcohols by using C6F5I(OCOCF3)(2), is described.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available