Variability of volcanic gas emissions during a crater lake heating cycle at Ruapehu Volcano, New Zealand

We present the first routine measurements of emissions (CO2, SO2, and H2S) from Ruapehu volcano, New Zealand during a crater lake heating cycle. Emissions were generally at a low level consistent with quiescent degassing of the volcano and the presence of a crater lake. Maximum concentrations ( similar to 3-4 kin downwind) during the highest measurement in May, 2004 were 14 ppm, 0. 3 7 ppm, and 7 ppb for CO2, SO2 and H2S, respectively. CO2 emissions varied between not detectable to 900 t d(-1) over periods of months. SO, was not detectable until February, but gradually increased to 35 t d(-1). Emissions of H2S were detected in April and May, although were < I t d(-1). The CO2/SO2 ratio in the plume was similar to 37 by weight for each measurement during the peak of the cycle suggesting that significant scrubbing Of SO2 occurs through the crater lake, and that a common source exists for both gases. Magma volumes estimated from CO2 emissions (0.001-0.004 km(3)) are consistent with eruptive volumes given repose periods of 20-30 years. Delays between peaks in crater-lake heating and degassing suggests that volcanic emissions do not primarily reside in the shallow hydrothermal system directly beneath the crater. Further data is needed to adequately model the system, but first indications of the travel time associated with the degassing cycle suggests that the gas resides at minimally 300 in depth beneath the crater lake. Depths greater than 300 in are consistent with the top of the single-phase steam zone in heat pipe models (200-700 in depth) or perhaps even below the plastic-brittle transition zone above the cooling magmas (> I kin deep). (c) 2006 Elsevier B.V. All rights reserved.