Journal
POLYHEDRON
Volume 25, Issue 9, Pages 2026-2032Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2006.01.006
Keywords
Schiff base metal complexes; mixed-valence dinuclear iron(II,III) complexes; carboxylate bridging ligands; Fe-57 Mossbauer spectroscopy; variable-temperature magnetic susceptibility studies; cyclic voltammetry
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Mixed valence dinuclear iron(II,III) complexes of the type [Fe2L2(H2O)(4)](NO3)(H2O)(3), where L is the dianion of a Schiff base ligand derived from alpha-amino acids (glycine and L-isolecine) and 5-bromosalicylaldehyde, have been prepared and characterised using different spectroscopic methods, magnetic susceptibility, conductivity, and electrochemical measurements. The mixed valence iron complexes can be described as hexacoordinated species, in which the metal ion is surrounded by water molecules, the salicylidenimine ligand and two bridging carboxylate groups. The presence of bromine as a substituent in the salicylaldehyde ring stabilises the mixed valence species. (c) 2006 Elsevier Ltd. All rights reserved.
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