Journal
ORGANIC LETTERS
Volume 8, Issue 13, Pages 2827-2829Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0609659
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This paper describes a catalytic asymmetric Simmons-Smith cyclopropanation of silyl enol ethers using dipeptide 2 as the ligand. A variety of optically active cyclopropyl silyl ethers can be obtained in high yields. Up to 96% ee was obtained. The dipeptide can be recovered after the reaction in good yield and reused without the loss of reactivity or enantioselectivity.
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