Journal
TETRAHEDRON
Volume 62, Issue 26, Pages 6289-6294Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2006.04.034
Keywords
tridentate NHC-Pd(II) complex; binaphthyl-2,2 '-diamine; cross-coupling reactions; Suzuki-Miyaura cross-coupling reaction; Heck reaction
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A novel tridentate NHC-Pd(II) complex derived from binaphthyl-2,2'-diamine (BINAM) has been synthesized and its structure has been characterized by single crystal X-ray diffraction. This NHC-Pd(II) complex was fairly effective in Suzuki and Heck-type cross-coupling reactions to give the products in good to excellent yields in most cases. (c) 2006 Elsevier Ltd. All rights reserved.
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