Preparation and characterization of magnetic polymeric composite particles by miniemulsion polymerization

A water-based magnetite ferrofluid, with an average size of about 10 nm, was prepared in a first step by the chemical coprecipitation of ferrous and ferric salts. Oil-based styrene (St) magnetite ferrofluid was obtained by the acidification of the water-based magnetite ferrofluid and the dispersion of the acidified magnetite in St. Magnetic polymeric composite particles (MPCPs) were prepared by miniemulsion polymerization in the presence of the oil-based St magnetite ferrofluid with hexadecane as a hydrophobe, 2,2'-azobisisobutyronitrile as an initiator, and sodium dodecyl sulfate as an emulsifier. Methacrylic acid was used as a comonomer, and hydroxyethyl cellulose and polyvinylpyrrolidone were used as aid stabilizers subsequently. With the aim of improving the encapsulation degree of magnetite, avoiding pure polymer particles and exposed magnetite particles, and obtaining the narrowest particle size distributions, the encapsulation conditions of magnetite were investigated in detail. The results show that miniemulsion polymerization is an effective method for encapsulating magnetite into a hydrophobic polymer successfully. Exposed magnetite particles and pure polymer particles can be avoided completely by the selection of the appropriate preparation conditions. All the resulting MPCPs exhibited superparamagnetism and possessed some magnetic response. (c) 2006 Wiley Periodicals, Inc.