Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 9, Issue 7, Pages 732-735Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2006.04.010
Keywords
nitriles; rhenium(IV) complexes; nucleophilic addition; metal-mediated reactions; dibenzylhydroxylamines; imino complexes
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The metal-mediated coupling between the acetonitriles in cis-[(ReCl4)-Cl-IV(MeCN)(2)] and the N,N-dibenzylhydroxylamines (R2NOH)-N-3 (R-3 = CH2Ph, CH2C6H4Cl-p) proceeds smoothly in CH2Cl2/MeCN at 20-25 degrees C for ca. 15 min to accomplish new imino species cis- [ReCl4{NH=C(Me) ONR23}(2)] (R-3 = CH2Ph, 1, CH2C6H4Cl-p, 2) in ca. 70% yield. The structures of the isolated compounds were based on elemental analyses (C, H, N), IR, FAB(+)-MS and on X-ray data for 1. (C) 2006 Published by Elsevier B.V.
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