Journal
PHYSICAL REVIEW B
Volume 74, Issue 4, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.74.045430
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The nitrogen interaction with Rh(100) was studied by combining high-energy resolution core level photoelectron spectroscopy and density functional calculations. Nitrogen-induced Rh3d(5/2) surface core level shifts depend on the N-Rh local geometrical configuration. The core level shifts are dominated by initial state effects and correlate strongly with the variation of the energy position of the surface atom-projected d-band center.
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