4.6 Article

Metallophthalocyanines catalyzed cyclopropanation of olefins with trimethylsilyldiazomethane: A facile and stereoselective synthesis of silylcyclopropanes

Journal

CATALYSIS COMMUNICATIONS
Volume 7, Issue 7, Pages 454-456

Publisher

ELSEVIER
DOI: 10.1016/j.catcom.2005.12.027

Keywords

silylcyclopropanes; metallophthalocyanines; trimethylsilyldiazomethane; cyclopropanation; olefin

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Metallophthalocyanines were found to be potent and versatile catalysts for the stereoselective synthesis of C-silyl cyclopropanes with high trans-selectivity by the reaction of olefins with trimethylsilyldiazomethane. (c) 2006 Elsevier B.V. All rights reserved.

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