4.7 Article

Mechanical and electrical properties of mechanically alloyed nanocrystalline Cu-Nb alloys

Journal

ACTA MATERIALIA
Volume 54, Issue 12, Pages 3333-3341

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.actamat.2006.03.021

Keywords

copper alloys; mechanical alloying; mechanical properties; electrical properties; nanocrystalline materials

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Nanocrystalline Cu and Cu-Nb alloys were prepared by the consolidation of inechanically alloyed powder. The alloys show a microstructure with a grain size below 50 nm. The microstructure of the Cu matrix remains stable even at elevated temperatures of up to 900 degrees C, whereas the Nb precipitates coarsen during annealing. The mechanical strength as well as the electrical conductivity depend on the grain size of the Cu matrix. which can be influenced by the temperature of (lie heat treatment, i.e.. a niechanical strength of about 1.6 GPa is measured for a Cu-10 at.%, Nb alloy which shows an electrical conductivity of about 10% LACS (international annealing copper standard) at room temperature. The main contribution to the mechanical strength of the alloys is attributed to the grain boundary strengthening in Cu referring to the Hall-Petch relation. which is quantified. The grain boundaries are also found to influence considerably the electrical resistivity. (c) 2006 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

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