Journal
CHEMISTRY LETTERS
Volume 35, Issue 7, Pages 790-791Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2006.790
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Aryl cyanides add to norbornene and norbornadiene under nickel catalysis to give (2R*,3S*)-3-aryt-2-cyanobicyclo[2.2.1]heptanes and (2R*,3S*)-3-aryl-2-cyanobicyclo[2.2.1]hept-5enes in good yields with a general substrate scope. On the other hand, the reaction of an aryl cyanide with triethoxy (vinyl)silane gives a Heck-type arylation product, suggesting the arylnickelation pathway in the catalytic cycle.
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