Journal
ORGANIC LETTERS
Volume 8, Issue 14, Pages 2965-2968Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol060847l
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- NCRR NIH HHS [P20 RR017716-01] Funding Source: Medline
- NIGMS NIH HHS [R01 GM068650-01A1] Funding Source: Medline
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The preparation of cyclopropene alpha-amino acids via the enantioselective desymmetrization of cyclopropene bis-carboxylic acid derivatives is described. The amino acids are stable to harsh reaction conditions, and a derivative has been incorporated into a tripeptide using conventional methods for peptide synthesis.
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