Journal
ORGANIC LETTERS
Volume 8, Issue 14, Pages 3149-3151Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0612298
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Manganese(III) acetate catalyzed allylic oxidation of alkenes to the corresponding enones was investigated, showing excellent regioselectivity and chemoselectivity (functional group compatibility). Delta(5)-Steroids were transformed into bioactive Delta(5)-en-7-ones under a nitrogen atmosphere, whereas simple alkenes were converted into the corresponding enones under an oxygen atmosphere in good yields.
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