Journal
ORGANIC LETTERS
Volume 8, Issue 14, Pages 3025-3027Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol060927p
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[GRAPHICS] In the presence of the optically active ketoiminatocobalt(II) complexes, the enantioselective borohydride reduction of benzophenones was successfully completed. The fluorine atom on the ortho position of the benzophenone and aryl ketones proved effective for obtaining high enantioselectivities. The combined use of modified lithium borohydride afforded the corresponding benzhydrols and arylcarbinols in high yield and high enantioselectivity (88-96% ee).
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