4.4 Article

Quasirelativistic theory I. Theory in terms of a quasi-relativistic operator

Journal

MOLECULAR PHYSICS
Volume 104, Issue 13-14, Pages 2225-2240

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1080/00268970600662481

Keywords

-

Ask authors/readers for more resources

In this first part of a general analysis of a quasi-relativistic theory, i.e. a relativistic theory for electrons only, the transformation of the Dirac operator to an operator with two-component spinor solutions is studied, while a forthcoming second part will be devoted to a transformation at matrix level. We start with a simple derivation of the key relation between the upper (phi) and lower (chi) components of the Dirac bispinor (psi) for both electrons and positrons. The three possible choices of a non-hermitian quasi-relativistic Hamiltonian L, a hermitian one (L) over tilde with non-unit metric, and a hermitian one L+ with unit metric are compared. The eigenfunctions of the first two are the upper components phi of psi while those of L+ are the Foldy-Wouthuysen-type spinors phi. A new derivation of the quasi-relativistic version of direct perturbation theory (DPT) is given, followed by the theory of quasi-relativistic effective Hamiltonians, both non-hermitian and hermitian ones. The classical Foldy-Wouthuysen transformation is then presented as the singular limit of quasi-relativistic effective Hamiltonians with the model space extended to the entire space of positive-energy states. Finally, the problems that arise for a Douglas-Kroll transformation or the regular approximation at operator level are studied in detail. In part 2, it will be shown that everything becomes much simpler if one performs the transformation from relativistic to quasi-relativistic theory at matrix level.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.4
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available