Journal
MACROMOLECULAR BIOSCIENCE
Volume 6, Issue 7, Pages 532-539Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/mabi.200600067
Keywords
atomic force microscopy (AFM); hydroxypropylcellulose (HPC); laser light scattering (LLS); nanofibers; self-association
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yThe aggregative behaviors of hydroxypropylcellulose (HPC) molecules in aqueous solution and on substrates have been,observed by employing laser light scattering (LLS) and, after deposition on a mica surface; atomic force microscopy (AFM). LLS, studies showed that the HPC molecules formed large aggregates through self-association when the concentration of the solution was above the critical concentration c(t), AFM measurements revealed that when a dilute aqueous solution of HPC molecules was deposited onto a mica substrate at a temperature below its lower critical solution temperature (LCST) thin nanofibers were formed with a height of 0.9 nm, whereas thick nanofibers were formed when an aqueous solution of HPC molecules was deposited onto a substrate above its LCST. Furthermore, the growth of nanofibers led to the formation of fan structures.
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