4.4 Article

Application of hydrophilic ionic liquids as co-solvents in chloroperoxidase catalyzed oxidations

Journal

TETRAHEDRON LETTERS
Volume 47, Issue 29, Pages 5089-5093

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2006.05.072

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The effect of hydrophilic ionic liquids (ILs) on the activity of chloroperoxidase (CPO) was checked through kinetic and stereochemical studies. The possibility to employ this enzyme in synthesis has been demonstrated investigating the chemo- and stereo selectivity of oxidation of phenyl methylsulfide in several citrate buffer-IL mixtures. (c) 2006 Elsevier Ltd. All rights reserved.

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