被撤回的出版物: First rhodium/phosphoramidite complex-catalyzed enantioselective isomerization of allylic alcohols into aldehydes (Retracted article. See vol. 52, pg. 5894, 2011)

Primary allylic alcohols are converted into chiral aldehydes in the presence of a catalytic amount (7 mol %) of a monodentate phosphoramidite rhodium catalyst. The aldehydes are isolated in high yields (84-89%) and moderate to good ee's (38-70%). A preliminary mechanistic study showed that the reaction proceeds through a 1,3-H migration pathway. (c) 2006 Elsevier Ltd. All rights reserved.