Journal
APPLIED CATALYSIS A-GENERAL
Volume 309, Issue 1, Pages 85-90Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcata.2006.04.033
Keywords
dialkyl peroxides; hydroperoxides; polymer-supported phase-transfer catalysts; triphase catalysis
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The synthesis of dialkyl peroxides from alkyl hydroperoxides and alkyl bromides in the presence of polymer-supported phase-transfer catalysts has been investigated. It was revealed that polymer-bound quaternary ammonium and polyethylene glycol catalysts were more active than their soluble forms. High yields (60-92%) of the products were obtained. The catalyst could be recycled several times with no appreciable loss of activity. (c) 2006 Elsevier B.V. All rights reserved.
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