4.2 Article Proceedings Paper

New tunable catalysts for olefin metathesis: Controlling the initiation through electronic factors

Journal

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 254, Issue 1-2, Pages 118-123

Publisher

ELSEVIER
DOI: 10.1016/j.molcata.2005.12.049

Keywords

ruthenium; metathesis; catalysis; catalyst activation; carbene complex

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Synthesis and screening of catalytic activity of two novel ruthenium carbene complexes 9 and 10 bearing substiments in 2-isopropoxybenzylidene ligand is described. These precatalysts constitute excellent tools for RCM and enyne metathesis by combining high stability with a possibility of their on-demand activation by heat and Bronsted (9) or Lewis acids (10). (c) 2006 Elsevier B.V. All rights reserved.

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