Journal
ORGANIC LETTERS
Volume 8, Issue 15, Pages 3323-3325Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0611393
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The reduction of aryl diazonium salts in the presence of nonactivated olefins provides rapid entry to carbodiazenylation products. The regioselective functionalization of double bonds is achieved in a one-pot process starting from aniline derivatives. Carboamination of olefins is possible via a two-step carbodiazenylation-hydrogenation sequence in which one aniline equivalent is recovered.
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