Journal
CHIRALITY
Volume 18, Issue 7, Pages 479-482Publisher
WILEY
DOI: 10.1002/chir.20273
Keywords
asymmetric autocatalysis; achiral silica gel; absolute asymmetric synthesis; 5-pyrimidyl alkanol; diisopropylzinc; spontaneous symmetry breaking
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An enantiomerically enriched pyrimidyl alkanol with either S or R configurations was obtained stochastically from the reaction between pyrimidine-5-carbaldehyde and diisopropylzinc in the presence of achiral silica gel in conjunction with asymmetric autocatalysis with amplification of chirality.
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