4.2 Article

Mixed-Kolbe electrolysis using solid-supported bases

Journal

ELECTROCHEMISTRY
Volume 74, Issue 8, Pages 615-617

Publisher

ELECTROCHEMICAL SOC JAPAN
DOI: 10.5796/electrochemistry.74.615

Keywords

carboxylic acid; mixed-Kolbe electrolysis; solid-supported base; supporting electrolyte

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We have successfully developed a novel mixed-Kolbe electrolysis system using solid-supported bases. Mixed-Kolbe electrolysis of carboxylic acids using solid-supported bases was carried out to provide the corresponding mixed-Kolbe products in moderate to good yields. In this system, solid-supported bases were recyclable even under high current density.

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