Journal
APPLIED CATALYSIS A-GENERAL
Volume 309, Issue 2, Pages 270-272Publisher
ELSEVIER
DOI: 10.1016/j.apcata.2006.05.015
Keywords
chromium-exchanged zeolite; Cr-E-ZSM-5; t-butyl hydroperoxide; alcohol oxidation; benzylic oxidation; leaching
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The oxidative properties of chromium-exchanged zeolite (CrE-ZSM-5) towards the oxidation of alcohols and benzylic methylene groups with t-butyl hydroperoxide have been evaluated. In most cases, high yields of ketones have been obtained. Experimental evidence is presented that these reactions were, at least in part, homogeneously catalyzed by leached chromium. (C) 2006 Elsevier B.V. All rights reserved.
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