Journal
REACTION KINETICS AND CATALYSIS LETTERS
Volume 88, Issue 2, Pages 315-323Publisher
SPRINGER
DOI: 10.1007/s11144-006-0067-6
Keywords
CuCl2/gamma-Al2O3; vinyl chloride; oxychlorination; KCl
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Effect of KCl on the structure and the catalytic properties of CuCl2/gamma-Al2O3 catalyst for ethane oxychlorination has been studied by means of solubility test, UV-vis spectroscopy, XRD, TPR, TEM and catalytic reaction. Addition of KCl decreases the interaction between active species CuCl2 and gamma-Al2O3 and increases the catalytic properties by accelerating the Cu(II) -> Cu(I) reduction step.
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