Journal
PROPELLANTS EXPLOSIVES PYROTECHNICS
Volume 31, Issue 4, Pages 253-262Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/prep.200600034
Keywords
akardite-II; daughter products; chemical stabilizer; gun propellant; rocket motor; ageing
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In this work, five akardite-II (AK-II) daughter products were produced and isolated. Their respective MS, NMR, IR and UV spectra were recorded. These five products were positively identified as: N-NO-AK-II, 2-NO2-AK-II, 4-NO2-AK-II, N-NO2-NO2-AK-II and N-NO-4-NO2-AK-II. An HPLC method giving baseline separation of 6 AK-II family products and 10 diphenylamine (DPA) family products is also described. Finally, preliminary results concerning the stability of AK-II daughter products are discussed.
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