Journal
SYNLETT
Volume -, Issue 12, Pages 1867-1870Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2006-947365
Keywords
boron; palladium; catalysis; cross-coupling; ligands
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The combination of Pd(dba)(2) and bis(2-di-tert-butylphospbinophenyl)ether has proven to be efficient for the crosscoupling of pinacolborane with aryl bromides and chlorides. The substrate scope is broad and the present system enables the synthesis of ortho-, meta-, and para-substituted electron-rich and -deficient arylboronates.
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