Journal
JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY
Volume 43, Issue 8, Pages 1215-1225Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/10601320600737393
Keywords
macroporous gels; ionic hydrogels; freezing; swelling; response rate
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A series of strong polyelectrolyte gels were prepared in aqueous solution, using the sodium salt of 2-acrylamido-2-methylpropane sulfonic acid (AMPS) as the monomer and N,N'-methylene(bis)acrylamide (BAAm) as a crosslinker. The gels were both prepared below (-22 degrees C) and above (25 degrees C) the bulk freezing temperature of the water, producing cryogels and hydrogels, respectively. The crosslinker (BAAm) content was set at 17 mol%, while the initial monomer concentration C o was varied over a wide range. It was found that, at -22 degrees C, a macroscopic network starts to form at an initial monomer concentration of as low as 0.1 w/v%. In contrast to the conventional hydrogels formed at 25 degrees C, the cryogels have a discontinuous morphology consisting of polyhedral pores of sizes 10(0) -10(2) mu m. The cryogels exhibit superfast swelling properties, as well as reversible swelling-deswelling cycles in water and acetone. An increase in the initial monomer concentration from 2.5 to 10% further increases the response rate of the cryogels due to the simultaneous increase of the porosity of the networks.
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