4.2 Article

Dimerization of styrene to 1,3-diphenyl-1-butene catalyzed by palladium-Lewis acid in ionic liquid

Journal

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 255, Issue 1-2, Pages 16-18

Publisher

ELSEVIER
DOI: 10.1016/j.molcata.2006.03.058

Keywords

dimerization of styrene; room temperature ionic liquid; Pd(OAc)(2)/Lewis acid catalyst

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Dimerization of styrene was investigated in ionic liquids and organic solvents with the catalysis of several palladium-Lewis acids catalyst systems. Pd(OAc)(2)/Cu(OTf)(2) and Pd(OAc)(2)/ln(OTf)(3) in 1-butyl-3-methylimidazolium hexafluorophosphate were found to be effective catalyst systems towards the dimerization of styrene to 1,3-diphenyl-l-butene at room temperature. (c) 2006 Elsevier B.V. All rights reserved.

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