Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 255, Issue 1-2, Pages 31-35Publisher
ELSEVIER
DOI: 10.1016/j.molcata.2006.03.060
Keywords
alcohol; aldehyde; aluminum chloride; arene; Friedel-Crafts alkylation; solvent-free; tandem reaction
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Tandem Friedel-Crafts reaction of arenes and aldehydes under the catalysis of Lewis acid was investigated. Both aromatic and aliphatic aldehydes underwent a tandem Friedel-Crafts alkylation with electron-rich arenes to afford 1,1,1-triaryl/1,1-diarylalkanes in the presence of anhydrous aluminum chloride under solvent-free conditions. The scope, limitation, and mechanism of the tandem reaction were also discussed. (c) 2006 Elsevier B.V. All rights reserved.
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