3.8 Article

Chitosan-supported imine palladacycle complex and its catalytic performance for Heck reaction

Journal

REACTION KINETICS AND CATALYSIS LETTERS
Volume 88, Issue 2, Pages 217-223

Publisher

AKADEMIAI KIADO
DOI: 10.1007/s11144-006-0055-x

Keywords

chitosan; imine palladacycle; Heck reaction; stereoselective synthesis

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A chitosan-supported imine palladacycle complex has been synthesized by salicylaldehyde via grafting on chitosan to form chitosan-Schiff base, followed by reacting with Li2PdCl4 in methanol. The catalyst has high activity and stereoselectivity for arylation of conjugate alkenes with aryl halides. This chitosan-supported imine palladium catalyst can be recovered and reused.

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