Journal
NEW JOURNAL OF CHEMISTRY
Volume 30, Issue 8, Pages 1207-1213Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b605087e
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A highly selective fluorescent sensor for fluoride, bis(2-hydroxy-1-naphthaldehyde)-2,6-pyridinedicarboxylic acid hydrazone (H-NP1) was synthesized and structurally characterized. UV-Vis and luminescent titrations of H-NP1 with F- demonstrated the presence of an H-NP1 center dot center dot center dot F- interaction species with association constant log K-# = 5.26 +/- 0.0 1. The sensor responded to fluoride ion through an excited-state intermolecular proton transfer (ESPT) mechanism with the emission band red-shifted and enhanced. For further studying the potential mechanism, binding-signaling transduction of related compound H-NP2, bis(2-hydroxy-l-naphthaldehyde)-1,3-benzenedicarboxylic acid hydrazone and two control compounds (H-NP3) and (H-NP4) derived from 1-naphthaldehyde was also investigated for comparison.
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