4.8 Article

A double INHIBIT logic gate employing configuration and fluorescence changes

Journal

ADVANCED MATERIALS
Volume 18, Issue 15, Pages 2035-2038

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200600235

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A lockable as well as double INHIBIT logic gate based on a [2]rotaxane employing configuration and fluorescence changes has been demonstrated (see figure). Importantly, the output 0 and 1 states of the current logic circuits represent several different supramolecular configurations. The photoisomerization process is completely reversible, making the shuttling motions of the cyclodextrin ring repeatable and accompanied by a reversible florescence signal.

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