Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 71, Issue 16, Pages 6269-6272Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo060708h
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A simple and efficient organocatalytic enantioselective hydrophosphonylation of imines to enantiomerically enriched alpha-amino phosphonates is reported. By using 10 mol % of quinine as the catalyst in the enantioselective addition of diethyl phosphite to N-Boc protected imines, alpha-amino phosphonates are obtained in moderate to good yields and with up to 94% ee.
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