4.5 Article

Novel lasing action in dye-doped polymer films coated on large pseudotabular Ag islands

Journal

JOURNAL OF PHYSICAL CHEMISTRY B
Volume 110, Issue 31, Pages 15052-15054

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jp062518g

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An similar to 15 mu m thick polymer film doped (similar to 5 mM) with a laser dye, when coated on large pseudotabular Ag islands and pumped by a nanosecond laser, generated a single sharp stimulated emission with a bandwidth down to 2.5 nm. We attribute this novel, low-threshold (similar to 1 mJ/cm(2)) lasing action to the surface-enhanced fluorescence of the dyes very near the Ag islands. This highly surface-sensitive lasing concept was supported by the fact that the lasing action was almost completely eliminated by separating the Ag islands and the dye-doped polymer film with a molecularly thin (similar to 14 angstrom) spacer.

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