Journal
PHYSICAL REVIEW LETTERS
Volume 97, Issue 6, Pages -Publisher
AMERICAN PHYSICAL SOC
DOI: 10.1103/PhysRevLett.97.065901
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Li-7 stimulated-echo NMR and classical relaxation NMR techniques are jointly used for the first time for a comprehensive investigation of Li diffusion in layer-structured Li0.7TiS2. One single 2D Li diffusion process was probed over a dynamic range of almost 10 orders of magnitude. So far, this is the largest dynamic range being measured by Li-7 NMR spectroscopy directly, i.e., without the help of a specific theoretical model. The jump rates obey a strict Arrhenius law, determined by an activation energy of 0.41(1) eV and a preexponential factor of 6.3(1)x10(12) s(-1), and range between 1x10(-1) s(-1) and 7.8x10(8) s(-1) (148-510 K). Ultraslow Li jumps in the kHz to sub-Hz range were measured directly by recording Li-7 spin-alignment correlation functions. The temperature and, in particular, the frequency dependence of the relaxation rates fully agree with results expected for 2D diffusion.
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