Crossover from stretched to compressed exponential relaxations in a polymer-based sponge phase

X-ray photon correlation spectroscopy was used to characterize the wave vector- and temperature-dependent dynamics of spontaneous thermal fluctuations in a sponge (L-3) phase that occurs in a blend of a symmetric poly(styrene-ethylene/butylene-styrene) triblock copolymer with a polystyrene homopolymer. Measurements of the intermediate scattering function reveal a crossover from stretched- to compressed-exponential relaxations as the temperature is lowered from 180 to 120 degrees C.