4.4 Article

Pd/C-Et3N-mediated catalytic hydrodechlormation of aromatic chlorides under mild conditions

Journal

TETRAHEDRON
Volume 62, Issue 33, Pages 7926-7933

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2006.05.025

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A mild and efficient one-pot procedure for the hydrodechlorination of aromatic chlorides using a Pd/C-Et3N system was developed. A variety of aromatic chlorides could be dechlorinated at room temperature and under ambient hydrogen pressure. Et3N activates the catalysis and is likely to work as a single electron donor in this system. (c) 2006 Elsevier Ltd. All rights reserved.

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