Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 110, Issue 32, Pages 15864-15868Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp0638437
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Polydiacetylenes (PDA) can take several colors, mostly red and blue, and blue-to-red color transitions are usually considered as transitions from a well ordered state to a disordered one. Recent work on single isolated PDA chains shows that this is not correct: red chains can be quasi-perfect quantum wires. The transition is between two different chain conformations, and each may, or may not, be perfectly ordered. Disorder, when it occurs, is a side-product of the transformation.
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