Journal
ORGANIC LETTERS
Volume 8, Issue 17, Pages 3709-3712Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol061292x
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A readily prepared bimetallic catalyst is capable of effecting epoxide carbonylation to produce beta-lactones at substantially lower CO pressures than previously reported catalyst systems. A functionally diverse array of beta-lactones is produced in excellent yields at CO pressures as low as 1 atm. This procedure allows for epoxide carbonylation on a multigram scale without the requirement of specialized, high-pressure equipment.
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