Journal
PHYSICAL REVIEW LETTERS
Volume 97, Issue 7, Pages -Publisher
AMERICAN PHYSICAL SOC
DOI: 10.1103/PhysRevLett.97.075502
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A thermodynamic diffuse interface analysis predicts that grain boundary transitions in solute absorption are coupled to localized structural order-disorder transitions. An example calculation of a planar grain boundary using a symmetric binary alloy shows that first-order boundary transitions can be predicted as a function of the crystallographic grain boundary misorientation and empirical gradient coefficients. The predictions are compared to published experimental observations.
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