Journal
SCIENCE
Volume 313, Issue 5789, Pages 961-962Publisher
AMER ASSOC ADVANCEMENT SCIENCE
DOI: 10.1126/science.1129309
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Anthraquinone molecules self-assemble on a Cu(111) surface into a large two-dimensional honeycomb network (root 304 x root 304 p)R23 degrees with pore diameters of approximate to 50 angstrom. The spontaneous formation of a pattern containing pores roughly five times larger than the size of the constituent molecules is unprecedented. The network originates from a delicate balance between substrate-mediated repulsion and intermolecular attraction involving an unusual chemical motif: hydrogen bonding between a carbonyl oxygen and an aromatic hydrogen atom. Substrate-mediated long-range adsorbate-adsorbate repulsion has been observed on anisotropic surfaces and in the context of the absence of pattern formation. Its applicability for the design of tailored molecular films is explored here.
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