Journal
INORGANIC CHEMISTRY
Volume 45, Issue 17, Pages 6595-6597Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic060969+
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An air-stable titanium-organic framework, prepared from Ti((OPr)-Pr-i)(4) and 1,4-butanediol, has been characterized via single-crystal X- ray diffraction, revealing a unique supramolecular structure. Its functionality as a highly active initiator for the ring-opening polymerization of cyclic esters is demonstrated. A discrete titanium trimer containing the related ligand (2R,3R)-2,3-butanediol has also been prepared, and it shows analogous activity as a polymerization initiator.
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