Journal
POLYHEDRON
Volume 25, Issue 12, Pages 2407-2414Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2006.02.003
Keywords
iridium(III) complex; red phosphorescent; photoluminescence; electroluminescence; organic light-emitting diode; triplet energy
Categories
Ask authors/readers for more resources
A series of trifluoromethyl-substituted 2-naphthalen-1-yl-pyridine ligands and the corresponding iridium complexes have been synthesized and characterized by spectroscopic methods as well as X-ray crystallography. Upon excitation at 470 nm, (4-fnapy)(2)Ir(acac) and (5-fnapY)(2)Ir(acac) emit red photoluminescence at 617 and 613 nm, respectively. Compared to (naPY)(2)Ir(acac), the introduction of trifluoromethyl substituents resulted in a significant bathochromic shift caused by a lowering of the LUMO levels. We propose that the bathochromic effect of the nitrogen atom on the pyrimidine ring should be much weaker than expected from the work of Chi et al. [Inorg. Chem. 44 (2005) 1344]. For a blend with 6 wt% of (5-fnapy)(2)Ir(acac), a brightness of 8600 cd m(-2) at 10.5 V is reached with Commission Internationale de L'Eclairage chromaticity coordinates of x = 0.65 and y = 0.35. (c) 2006 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available