Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 110, Issue 33, Pages 16205-16207Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp062710i
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We use the Flory-Huggins theory to demonstrate conditions of extra solvent power of ionic liquids. The short-range interactions between anions, cations, and molecules of the solute are taken into account. We find that solvent power of the ionic liquids is enhanced if non-Coulomb interactions between the anions and cations are repulsive. The mechanism responsible for the extra solvent power is related to the shielding of the anion-cation interactions by the molecules of the solute.
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