Journal
PHYSICAL REVIEW LETTERS
Volume 97, Issue 8, Pages -Publisher
AMERICAN PHYSICAL SOC
DOI: 10.1103/PhysRevLett.97.086102
Keywords
-
Categories
Ask authors/readers for more resources
Recently, a hardness similar to that of diamond has been reported for a quasiternary, nitride-based nanocomposite. The related, quasibinary nanocomposite nc-TiN/a-Si3N4, which may be regarded as the prototype of the family of superhard nc-metal-N/a-Si3N4 systems, also exhibits a significant hardness enhancement. Extensive density-functional theory calculations indicate that the superhardness is related to the preferential formation of TiN(111) polar interfaces with a thin beta-Si3N4-derived layer. The strength of TiN in the < 111 > direction is similar to that of the weakest bonding direction in diamond. Oxygen impurities cause a significant reduction of the interface strength.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available