Journal
TETRAHEDRON LETTERS
Volume 47, Issue 35, Pages 6173-6177Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2006.06.165
Keywords
Dual Si-H effect; platinum; reduction; selfencapsulation
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Combination of commercially available platinum catalysts with siloxanes containing more than two Si-H groups is found to be an efficient catalyst system for the reduction of carboxamides to amines. In particular, facile removal of silicon and platinum residues from the product can be achieved by the use of polymethylhydrosiloxanes as reducing reagents. (c) 2006 Elsevier Ltd. All rights reserved.
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