Journal
ORGANIC LETTERS
Volume 8, Issue 18, Pages 3911-3914Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol061370g
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Organoboron-based diarylethene was successfully synthesized and exhibited photochromic property. Furthermore, its photochromic property can be modulated by a fluoride ion. The absorption maximum of the photostationary state shifted from 655 to 490 nm upon addition of a fluoride ion. The modulation mechanism is attributed to the special Lewis acid-base interaction between a trivalent boron atom and a fluoride ion.
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